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National Institute of Standards and Technology nist chemical kinetics database
Nist Chemical Kinetics Database, supplied by National Institute of Standards and Technology, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
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Article Title: Tetrahydroxybenzoquinone-Based Two-Dimensional Conductive Metal–Organic Framework via π-d Conjugation Modulation for Enhanced Oxygen Evolution Reaction
Article Snippet: According to the National Institute of Standards and Technology (NIST) Chemical Kinetics Database, the standard molar entropies of H2 and O2 under standard conditions (298.15 K, 1 atm) are 130.68 J/(mol·K) and 205.14 J/(mol·K), respectively.

Article Title: The Roles of Hydroxyl Radicals and Superoxide in Oxidizing Aqueous Benzyl Alcohol Under Ultrasound Irradiation.
Article Snippet: The abatement of aromatic pollutants in water requires their oxidation to nontoxic products by resource-intensive reactions with hydroxyl radicals (*OH).. We elucidate the mechanisms of *OH-induced aromatic ring degradation by combining kinetic measurements, electron paramagnetic resonance spectroscopy, density functional theory calculations, and kinetic modelling.. We demonstrate that benzyl alcohol (a model aromatic compound) is oxidized by *OH radicals, generated by ultrasonic irradiation in an O2-rich environment, into aromatic compounds (benzaldehyde and phenol derivatives) and C1@C2 oxygenates (formic acid, glyoxal, and oxalic acid).

Article Title: On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity
Article Snippet: RO2 −→ wallb 2.5× 10−3 a Except the NO2 photolysis and wall loss rates (s−1), all the other reaction rates (cm3 s−1) are adapted from the NIST (National Institute of Standards and Technology) Chemical Kinetics Database (for more information see https://kinetics.nist.gov/kinetics/index.jsp (last access: 25 August 2023). b In our model, we only considered RO2 with a wall loss lifetime of 400 s (Peräkylä et al., 2020).

Article Title: Organic carbon dry deposition outpaces atmospheric processing with unaccounted implications for air quality and freshwater ecosystems.
Article Snippet: A. Manion, R. e. huie, R. d. Levin, d. R. Burgess Jr., v. L. Orkin, W. tsang, W. S. McGivern, J. W. hudgens, v. d. Knyazev, d. B. Atkinson, e. chai, A. M. tereza, c.- Y. Lin, t. c. Allison, W. G. Mallard, F. Westley, J. t. herron, R. F. hampson, d. h. Frizzell, NIST Chemical Kinetics Database, NIST Standard Reference Database 17, Version 7.0 (Web Version) (national institute of Standards and technology, 2015); http://kinetics.nist.gov/.

Article Title: Spatiotemporal Variations in Ozone and Carbon Dioxide Concentrations in a HVAC System of a LEED-Certified Office Building
Article Snippet: Indoor air quality (IAQ) is crucial for the health, well-being, and productivity of office occupants.. IAQ is strongly influenced by occupancy and the operational mode of the heating, ventilation, and air conditioning (HVAC) system.. This study investigates the spatiotemporal variations in ozone (O3) and carbon dioxide (CO2) concentrations throughout the HVAC system of a LEED-Certified office building.

Article Title: Reactive Radical Etching of Quartz by Microwave Activated CH 4 /H 2 Plasmas Promotes Gas Phase Nanoparticle Formation.
Article Snippet: An attenuation of visible probe radiation identified in earlier absorption studies of microwave plasma-activated CH4/ H2/Ar gas mixtures is shown to arise from nanoparticles in underpumped regions on opposing sides of a reactor used for diamond chemical vapor deposition.. The present modeling studies highlight (i) ejection of Si-containing species into the gas phase by reactive radical etching of the quartz window through which the microwave radiation enters the reactor, enabled by suitably high window temperatures (TSiO2) and the synergistic action of near-window H atoms and CyHx radicals; (ii) subsequent processing of the ejected material, some of which are transported to and accumulate in stagnation regions in the entrance to the reactor side arms; and (iii) the importance of Si in facilitating homogeneous gas phase nucleation, clustering, and nanoparticle growth in these regions.. The observed attenuation, its probe wavelength dependence, and its variations with changes in process conditions can all be rationalized by a combination of absorption and scattering contributions from Si/C/H containing nanoparticles with diameters d in the range of 50−100 nm.

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Article Title: Characterizing sources and health risks of airborne Carbonyl compounds in a subtropical coastal atmosphere in South China.
Article Snippet: Carbonyl compounds are critical air pollutants with adverse impacts on regional air quality and human health.. This study presents a pioneering analysis of spatiotemporal distribution, source appointment, and health risk assessments of carbonyl compounds in the coastal marine atmosphere.. By combining ship-borne and groundbased sampling followed with enhanced chemical analysis, 39 carbonyls were identified and quantified in the coastal Hong Kong.



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